Spider-Man Was Train By Captain America in Comic Once in Friendly Neighbourhood Spider-Man in Vol 1#1 2005.

Then Later in Ultimate Spider-Man By He's Uncle Ben Once in the Comic Shield And By Iron Fist in Cartoon Been There Done that

And Later By Shang-Chi Once in Comic in 2011 in 3 Comics in the Way of the Spider.

In The Spider-Man Cartoon Once in the 80S Shang-Chi Was name Master of Kung Fu.

He Also Show in Marvel Adventures of Spider-Man in Comic at Peter's School.

So Wonder if The Spider Team Can Get Train By Shang-Chi and He's Sister